HNO3 + Cu = H2O + NO + CuNO32

HNO_3 nitric acid + Cu copper ⟶ H_2O water + NO nitric oxide + CuNO32

Balance the chemical equation algebraically: HNO_3 + Cu ⟶ H_2O + NO + CuNO32 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 HNO_3 + c_2 Cu ⟶ c_3 H_2O + c_4 NO + c_5 CuNO32 Set the number of atoms in the reactants equal to the number of atoms in the products for H, N, O and Cu: H: | c_1 = 2 c_3 N: | c_1 = c_4 + c_5 O: | 3 c_1 = c_3 + c_4 + 32 c_5 Cu: | c_2 = c_5 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_2 = 1 and solve the system of equations for the remaining coefficients: c_1 = 62/3 c_2 = 1 c_3 = 31/3 c_4 = 59/3 c_5 = 1 Multiply by the least common denominator, 3, to eliminate fractional coefficients: c_1 = 62 c_2 = 3 c_3 = 31 c_4 = 59 c_5 = 3 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 62 HNO_3 + 3 Cu ⟶ 31 H_2O + 59 NO + 3 CuNO32

+ ⟶ + + CuNO32

nitric acid + copper ⟶ water + nitric oxide + CuNO32

Construct the equilibrium constant, K, expression for: HNO_3 + Cu ⟶ H_2O + NO + CuNO32 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 62 HNO_3 + 3 Cu ⟶ 31 H_2O + 59 NO + 3 CuNO32 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i HNO_3 | 62 | -62 Cu | 3 | -3 H_2O | 31 | 31 NO | 59 | 59 CuNO32 | 3 | 3 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression HNO_3 | 62 | -62 | ([HNO3])^(-62) Cu | 3 | -3 | ([Cu])^(-3) H_2O | 31 | 31 | ([H2O])^31 NO | 59 | 59 | ([NO])^59 CuNO32 | 3 | 3 | ([CuNO32])^3 The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([HNO3])^(-62) ([Cu])^(-3) ([H2O])^31 ([NO])^59 ([CuNO32])^3 = (([H2O])^31 ([NO])^59 ([CuNO32])^3)/(([HNO3])^62 ([Cu])^3)

Construct the rate of reaction expression for: HNO_3 + Cu ⟶ H_2O + NO + CuNO32 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 62 HNO_3 + 3 Cu ⟶ 31 H_2O + 59 NO + 3 CuNO32 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i HNO_3 | 62 | -62 Cu | 3 | -3 H_2O | 31 | 31 NO | 59 | 59 CuNO32 | 3 | 3 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term HNO_3 | 62 | -62 | -1/62 (Δ[HNO3])/(Δt) Cu | 3 | -3 | -1/3 (Δ[Cu])/(Δt) H_2O | 31 | 31 | 1/31 (Δ[H2O])/(Δt) NO | 59 | 59 | 1/59 (Δ[NO])/(Δt) CuNO32 | 3 | 3 | 1/3 (Δ[CuNO32])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/62 (Δ[HNO3])/(Δt) = -1/3 (Δ[Cu])/(Δt) = 1/31 (Δ[H2O])/(Δt) = 1/59 (Δ[NO])/(Δt) = 1/3 (Δ[CuNO32])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| nitric acid | copper | water | nitric oxide | CuNO32 formula | HNO_3 | Cu | H_2O | NO | CuNO32 name | nitric acid | copper | water | nitric oxide |

| nitric acid | copper | water | nitric oxide | CuNO32 molar mass | 63.012 g/mol | 63.546 g/mol | 18.015 g/mol | 30.006 g/mol | 589.52 g/mol phase | liquid (at STP) | solid (at STP) | liquid (at STP) | gas (at STP) | melting point | -41.6 °C | 1083 °C | 0 °C | -163.6 °C | boiling point | 83 °C | 2567 °C | 99.9839 °C | -151.7 °C | density | 1.5129 g/cm^3 | 8.96 g/cm^3 | 1 g/cm^3 | 0.001226 g/cm^3 (at 25 °C) | solubility in water | miscible | insoluble | | | surface tension | | | 0.0728 N/m | | dynamic viscosity | 7.6×10^-4 Pa s (at 25 °C) | | 8.9×10^-4 Pa s (at 25 °C) | 1.911×10^-5 Pa s (at 25 °C) | odor | | odorless | odorless | |