FeCl2 + K2S = KCl + FeS

FeCl_2 iron(II) chloride + K2S ⟶ KCl potassium chloride + FeS ferrous sulfide

Balance the chemical equation algebraically: FeCl_2 + K2S ⟶ KCl + FeS Add stoichiometric coefficients, c_i, to the reactants and products: c_1 FeCl_2 + c_2 K2S ⟶ c_3 KCl + c_4 FeS Set the number of atoms in the reactants equal to the number of atoms in the products for Cl, Fe, K and S: Cl: | 2 c_1 = c_3 Fe: | c_1 = c_4 K: | 2 c_2 = c_3 S: | c_2 = c_4 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 c_3 = 2 c_4 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | FeCl_2 + K2S ⟶ 2 KCl + FeS

+ K2S ⟶ +

iron(II) chloride + K2S ⟶ potassium chloride + ferrous sulfide

Construct the equilibrium constant, K, expression for: FeCl_2 + K2S ⟶ KCl + FeS Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: FeCl_2 + K2S ⟶ 2 KCl + FeS Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i FeCl_2 | 1 | -1 K2S | 1 | -1 KCl | 2 | 2 FeS | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression FeCl_2 | 1 | -1 | ([FeCl2])^(-1) K2S | 1 | -1 | ([K2S])^(-1) KCl | 2 | 2 | ([KCl])^2 FeS | 1 | 1 | [FeS] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([FeCl2])^(-1) ([K2S])^(-1) ([KCl])^2 [FeS] = (([KCl])^2 [FeS])/([FeCl2] [K2S])

Construct the rate of reaction expression for: FeCl_2 + K2S ⟶ KCl + FeS Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: FeCl_2 + K2S ⟶ 2 KCl + FeS Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i FeCl_2 | 1 | -1 K2S | 1 | -1 KCl | 2 | 2 FeS | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term FeCl_2 | 1 | -1 | -(Δ[FeCl2])/(Δt) K2S | 1 | -1 | -(Δ[K2S])/(Δt) KCl | 2 | 2 | 1/2 (Δ[KCl])/(Δt) FeS | 1 | 1 | (Δ[FeS])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[FeCl2])/(Δt) = -(Δ[K2S])/(Δt) = 1/2 (Δ[KCl])/(Δt) = (Δ[FeS])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| iron(II) chloride | K2S | potassium chloride | ferrous sulfide formula | FeCl_2 | K2S | KCl | FeS Hill formula | Cl_2Fe | K2S | ClK | FeS name | iron(II) chloride | | potassium chloride | ferrous sulfide IUPAC name | dichloroiron | | potassium chloride |

| iron(II) chloride | K2S | potassium chloride | ferrous sulfide molar mass | 126.7 g/mol | 110.26 g/mol | 74.55 g/mol | 87.9 g/mol phase | solid (at STP) | | solid (at STP) | solid (at STP) melting point | 677 °C | | 770 °C | 1195 °C boiling point | | | 1420 °C | density | 3.16 g/cm^3 | | 1.98 g/cm^3 | 4.84 g/cm^3 solubility in water | | | soluble | insoluble dynamic viscosity | | | | 0.00343 Pa s (at 1250 °C) odor | | | odorless |