Input interpretation
![acetyl chloride](../image_source/42cd95761700b3a4a956910d1237e0ed.png)
acetyl chloride
Chemical names and formulas
![formula | CH_3COCl Hill formula | C_2H_3ClO name | acetyl chloride alternate names | acetic acid chloride | acetic acid monochloride | acetic chloride | ethanoyl chloride mass fractions | C (carbon) 30.6% | Cl (chlorine) 45.2% | H (hydrogen) 3.85% | O (oxygen) 20.4%](../image_source/da02bf80f3445b700617552c075040f0.png)
formula | CH_3COCl Hill formula | C_2H_3ClO name | acetyl chloride alternate names | acetic acid chloride | acetic acid monochloride | acetic chloride | ethanoyl chloride mass fractions | C (carbon) 30.6% | Cl (chlorine) 45.2% | H (hydrogen) 3.85% | O (oxygen) 20.4%
Lewis structure
![Draw the Lewis structure of acetyl chloride. Start by drawing the overall structure of the molecule, ignoring potential double and triple bonds: Count the total valence electrons of the carbon (n_C, val = 4), chlorine (n_Cl, val = 7), hydrogen (n_H, val = 1), and oxygen (n_O, val = 6) atoms: 2 n_C, val + n_Cl, val + 3 n_H, val + n_O, val = 24 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), chlorine (n_Cl, full = 8), hydrogen (n_H, full = 2), and oxygen (n_O, full = 8): 2 n_C, full + n_Cl, full + 3 n_H, full + n_O, full = 38 Subtracting these two numbers shows that 38 - 24 = 14 bonding electrons are needed. Each bond has two electrons, so in addition to the 6 bonds already present in the diagram add 1 bond. To minimize formal charge oxygen wants 2 bonds and carbon wants 4 bonds. Identify the atoms that want additional bonds and the number of electrons remaining on each atom: Fill in the 1 bond by pairing electrons between adjacent highlighted atoms: Answer: | |](../image_source/7e371ead27a3843610108f50a1235b34.png)
Draw the Lewis structure of acetyl chloride. Start by drawing the overall structure of the molecule, ignoring potential double and triple bonds: Count the total valence electrons of the carbon (n_C, val = 4), chlorine (n_Cl, val = 7), hydrogen (n_H, val = 1), and oxygen (n_O, val = 6) atoms: 2 n_C, val + n_Cl, val + 3 n_H, val + n_O, val = 24 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), chlorine (n_Cl, full = 8), hydrogen (n_H, full = 2), and oxygen (n_O, full = 8): 2 n_C, full + n_Cl, full + 3 n_H, full + n_O, full = 38 Subtracting these two numbers shows that 38 - 24 = 14 bonding electrons are needed. Each bond has two electrons, so in addition to the 6 bonds already present in the diagram add 1 bond. To minimize formal charge oxygen wants 2 bonds and carbon wants 4 bonds. Identify the atoms that want additional bonds and the number of electrons remaining on each atom: Fill in the 1 bond by pairing electrons between adjacent highlighted atoms: Answer: | |
3D structure
![3D structure](../image_source/0182278fcb453e20ec19276d6a76467b.png)
3D structure
Basic properties
![molar mass | 78.5 g/mol phase | liquid (at STP) melting point | -112 °C boiling point | 52 °C density | 1.104 g/cm^3 solubility in water | insoluble](../image_source/117012aa6d0edb78e0b1998ad58717e2.png)
molar mass | 78.5 g/mol phase | liquid (at STP) melting point | -112 °C boiling point | 52 °C density | 1.104 g/cm^3 solubility in water | insoluble
Units
Liquid properties (at STP)
![density | 1.104 g/cm^3 vapor pressure | 604.4 mmHg dynamic viscosity | 3.68×10^-4 Pa s (at 25 °C) surface tension | 0.0267 N/m refractive index | 1.389](../image_source/0c695bda88d565557604fefdbfa23e1e.png)
density | 1.104 g/cm^3 vapor pressure | 604.4 mmHg dynamic viscosity | 3.68×10^-4 Pa s (at 25 °C) surface tension | 0.0267 N/m refractive index | 1.389
Units
Thermodynamic properties
![specific heat capacity c_p | gas | 0.8637 J/(g K) | liquid | 1.491 J/(g K) molar heat capacity c_p | gas | 67.8 J/(mol K) | liquid | 117 J/(mol K) specific free energy of formation Δ_fG° | gas | -2.622 kJ/g | liquid | -2.65 kJ/g molar free energy of formation Δ_fG° | gas | -205.8 kJ/mol | liquid | -208 kJ/mol molar heat of vaporization | 28.64 kJ/mol | specific heat of vaporization | 0.3649 kJ/g | molar heat of combustion | 1083 kJ/mol | specific heat of combustion | 13.8 kJ/g | critical temperature | 519 K | critical pressure | 5.83 MPa | (at STP)](../image_source/35df8d925602637fe7611340ddba9f19.png)
specific heat capacity c_p | gas | 0.8637 J/(g K) | liquid | 1.491 J/(g K) molar heat capacity c_p | gas | 67.8 J/(mol K) | liquid | 117 J/(mol K) specific free energy of formation Δ_fG° | gas | -2.622 kJ/g | liquid | -2.65 kJ/g molar free energy of formation Δ_fG° | gas | -205.8 kJ/mol | liquid | -208 kJ/mol molar heat of vaporization | 28.64 kJ/mol | specific heat of vaporization | 0.3649 kJ/g | molar heat of combustion | 1083 kJ/mol | specific heat of combustion | 13.8 kJ/g | critical temperature | 519 K | critical pressure | 5.83 MPa | (at STP)
Chemical identifiers
![CAS number | 75-36-5 Beilstein number | 605303 PubChem CID number | 6367 PubChem SID number | 24859250 SMILES identifier | CC(=O)Cl InChI identifier | InChI=1/C2H3ClO/c1-2(3)4/h1H3 RTECS number | AO6390000 MDL number | MFCD00000719](../image_source/7e71d6ef0d09cf474942b62bc6bbe3a1.png)
CAS number | 75-36-5 Beilstein number | 605303 PubChem CID number | 6367 PubChem SID number | 24859250 SMILES identifier | CC(=O)Cl InChI identifier | InChI=1/C2H3ClO/c1-2(3)4/h1H3 RTECS number | AO6390000 MDL number | MFCD00000719
NFPA label
![NFPA label](../image_source/5e3c53fa8b17a30465c5ed8905de9173.png)
NFPA label
![NFPA health rating | 3 NFPA fire rating | 3 NFPA reactivity rating | 2 NFPA hazards | water reactive](../image_source/05eaa9934978b47ec7bbf99d0c13fa48.png)
NFPA health rating | 3 NFPA fire rating | 3 NFPA reactivity rating | 2 NFPA hazards | water reactive
Safety properties
![flash point | 4.444 °C autoignition point | 390 °C lower explosive limit | 7.3% (concentration in air) upper explosive limit | 19% (concentration in air)](../image_source/cf12a00ff966222d192220892eafd30d.png)
flash point | 4.444 °C autoignition point | 390 °C lower explosive limit | 7.3% (concentration in air) upper explosive limit | 19% (concentration in air)
![DOT hazard class | 3 DOT numbers | 1717](../image_source/9ff4c702c78e4d0f58582cf322eb6ad7.png)
DOT hazard class | 3 DOT numbers | 1717
Toxicity properties
![RTECS classes | mutagen | human data](../image_source/30d369929d224b7b191532ef33145e7d.png)
RTECS classes | mutagen | human data