O2 + Cl2 = Cl2O7

oxygen + chlorine ⟶ dichlorine heptoxide

Balance the chemical equation algebraically: + ⟶ Add stoichiometric coefficients, c_i, to the reactants and products: c_1 + c_2 ⟶ c_3 Set the number of atoms in the reactants equal to the number of atoms in the products for O and Cl: O: | 2 c_1 = 7 c_3 Cl: | 2 c_2 = 2 c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_2 = 1 and solve the system of equations for the remaining coefficients: c_1 = 7/2 c_2 = 1 c_3 = 1 Multiply by the least common denominator, 2, to eliminate fractional coefficients: c_1 = 7 c_2 = 2 c_3 = 2 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 7 + 2 ⟶ 2

+ ⟶

oxygen + chlorine ⟶ dichlorine heptoxide

Construct the equilibrium constant, K, expression for: + ⟶ Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 7 + 2 ⟶ 2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i | 7 | -7 | 2 | -2 | 2 | 2 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression | 7 | -7 | ([O2])^(-7) | 2 | -2 | ([Cl2])^(-2) | 2 | 2 | ([Cl2O7])^2 The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([O2])^(-7) ([Cl2])^(-2) ([Cl2O7])^2 = ([Cl2O7])^2/(([O2])^7 ([Cl2])^2)

Construct the rate of reaction expression for: + ⟶ Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 7 + 2 ⟶ 2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i | 7 | -7 | 2 | -2 | 2 | 2 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term | 7 | -7 | -1/7 (Δ[O2])/(Δt) | 2 | -2 | -1/2 (Δ[Cl2])/(Δt) | 2 | 2 | 1/2 (Δ[Cl2O7])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/7 (Δ[O2])/(Δt) = -1/2 (Δ[Cl2])/(Δt) = 1/2 (Δ[Cl2O7])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| oxygen | chlorine | dichlorine heptoxide Hill formula | O_2 | Cl_2 | Cl_2O_7 name | oxygen | chlorine | dichlorine heptoxide IUPAC name | molecular oxygen | molecular chlorine | perchloryl perchlorate

| oxygen | chlorine | dichlorine heptoxide molar mass | 31.998 g/mol | 70.9 g/mol | 182.9 g/mol phase | gas (at STP) | gas (at STP) | melting point | -218 °C | -101 °C | -91.5 °C boiling point | -183 °C | -34 °C | 82 °C density | 0.001429 g/cm^3 (at 0 °C) | 0.003214 g/cm^3 (at 0 °C) | 1.9 g/cm^3 solubility in water | | | reacts surface tension | 0.01347 N/m | | dynamic viscosity | 2.055×10^-5 Pa s (at 25 °C) | | odor | odorless | |