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amyl chloride

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amyl chloride
amyl chloride

Chemical names and formulas

formula | CH_3(CH_2)_4Cl Hill formula | C_5H_11Cl name | amyl chloride IUPAC name | 1-chloropentane alternate names | 1-chloropentane | N-amyl chloride | N-pentyl chloride | pentane, 1-chloro- | pentyl chloride mass fractions | C (carbon) 56.3% | Cl (chlorine) 33.3% | H (hydrogen) 10.4%
formula | CH_3(CH_2)_4Cl Hill formula | C_5H_11Cl name | amyl chloride IUPAC name | 1-chloropentane alternate names | 1-chloropentane | N-amyl chloride | N-pentyl chloride | pentane, 1-chloro- | pentyl chloride mass fractions | C (carbon) 56.3% | Cl (chlorine) 33.3% | H (hydrogen) 10.4%

Lewis structure

Draw the Lewis structure of amyl chloride. Start by drawing the overall structure of the molecule:  Count the total valence electrons of the carbon (n_C, val = 4), chlorine (n_Cl, val = 7), and hydrogen (n_H, val = 1) atoms: 5 n_C, val + n_Cl, val + 11 n_H, val = 38 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), chlorine (n_Cl, full = 8), and hydrogen (n_H, full = 2): 5 n_C, full + n_Cl, full + 11 n_H, full = 70 Subtracting these two numbers shows that 70 - 38 = 32 bonding electrons are needed. Each bond has two electrons, so the above diagram has all the necessary bonds. There are 16 bonds and hence 32 bonding electrons in the diagram. Lastly, fill in the remaining unbonded electrons on each atom. In total, there remain 38 - 32 = 6 electrons left to draw: Answer: |   |
Draw the Lewis structure of amyl chloride. Start by drawing the overall structure of the molecule: Count the total valence electrons of the carbon (n_C, val = 4), chlorine (n_Cl, val = 7), and hydrogen (n_H, val = 1) atoms: 5 n_C, val + n_Cl, val + 11 n_H, val = 38 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), chlorine (n_Cl, full = 8), and hydrogen (n_H, full = 2): 5 n_C, full + n_Cl, full + 11 n_H, full = 70 Subtracting these two numbers shows that 70 - 38 = 32 bonding electrons are needed. Each bond has two electrons, so the above diagram has all the necessary bonds. There are 16 bonds and hence 32 bonding electrons in the diagram. Lastly, fill in the remaining unbonded electrons on each atom. In total, there remain 38 - 32 = 6 electrons left to draw: Answer: | |

3D structure

3D structure
3D structure

Basic properties

molar mass | 106.6 g/mol phase | liquid (at STP) melting point | -99 °C boiling point | 107.5 °C density | 0.882 g/cm^3 solubility in water | insoluble
molar mass | 106.6 g/mol phase | liquid (at STP) melting point | -99 °C boiling point | 107.5 °C density | 0.882 g/cm^3 solubility in water | insoluble

Units

Liquid properties (at STP)

density | 0.882 g/cm^3 vapor pressure | 32 mmHg (at 25 °C) dynamic viscosity | 5.8×10^-6 Pa s (at 20 °C) surface tension | 0.02515 N/m refractive index | 1.412
density | 0.882 g/cm^3 vapor pressure | 32 mmHg (at 25 °C) dynamic viscosity | 5.8×10^-6 Pa s (at 20 °C) surface tension | 0.02515 N/m refractive index | 1.412

Units

Thermodynamic properties

specific heat of formation Δ_fH° | gas | -1.641 kJ/g molar heat of formation Δ_fH° | gas | -174.9 kJ/mol molar heat of vaporization | 38.1 kJ/mol |  specific heat of vaporization | 0.357 kJ/g |  molar heat of combustion | 3354 kJ/mol |  specific heat of combustion | 31.47 kJ/g |  critical temperature | 571 K |  (at STP)
specific heat of formation Δ_fH° | gas | -1.641 kJ/g molar heat of formation Δ_fH° | gas | -174.9 kJ/mol molar heat of vaporization | 38.1 kJ/mol | specific heat of vaporization | 0.357 kJ/g | molar heat of combustion | 3354 kJ/mol | specific heat of combustion | 31.47 kJ/g | critical temperature | 571 K | (at STP)

Chemical identifiers

CAS number | 543-59-9 Beilstein number | 1696936 PubChem CID number | 10977 PubChem SID number | 24854299 SMILES identifier | CCCCCCl InChI identifier | InChI=1/C5H11Cl/c1-2-3-4-5-6/h2-5H2, 1H3 MDL number | MFCD00001015
CAS number | 543-59-9 Beilstein number | 1696936 PubChem CID number | 10977 PubChem SID number | 24854299 SMILES identifier | CCCCCCl InChI identifier | InChI=1/C5H11Cl/c1-2-3-4-5-6/h2-5H2, 1H3 MDL number | MFCD00001015

NFPA label

NFPA label
NFPA label
NFPA health rating | 1 NFPA fire rating | 3 NFPA reactivity rating | 0
NFPA health rating | 1 NFPA fire rating | 3 NFPA reactivity rating | 0

Safety properties

flash point | 11.11 °C autoignition point | 220 °C lower explosive limit | 1.4% (concentration in air) upper explosive limit | 8.6% (concentration in air)
flash point | 11.11 °C autoignition point | 220 °C lower explosive limit | 1.4% (concentration in air) upper explosive limit | 8.6% (concentration in air)
DOT hazard class | 3 DOT numbers | 1107
DOT hazard class | 3 DOT numbers | 1107