H2O + SiCl4 = HCl + H4SiO4

H_2O water + SiCl_4 silicon tetrachloride ⟶ HCl hydrogen chloride + H_4O_4Si_1 orthosilicic acid

Balance the chemical equation algebraically: H_2O + SiCl_4 ⟶ HCl + H_4O_4Si_1 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 H_2O + c_2 SiCl_4 ⟶ c_3 HCl + c_4 H_4O_4Si_1 Set the number of atoms in the reactants equal to the number of atoms in the products for H, O, Cl and Si: H: | 2 c_1 = c_3 + 4 c_4 O: | c_1 = 4 c_4 Cl: | 4 c_2 = c_3 Si: | c_2 = c_4 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_2 = 1 and solve the system of equations for the remaining coefficients: c_1 = 4 c_2 = 1 c_3 = 4 c_4 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 4 H_2O + SiCl_4 ⟶ 4 HCl + H_4O_4Si_1

+ ⟶ +

water + silicon tetrachloride ⟶ hydrogen chloride + orthosilicic acid

Construct the equilibrium constant, K, expression for: H_2O + SiCl_4 ⟶ HCl + H_4O_4Si_1 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 4 H_2O + SiCl_4 ⟶ 4 HCl + H_4O_4Si_1 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i H_2O | 4 | -4 SiCl_4 | 1 | -1 HCl | 4 | 4 H_4O_4Si_1 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression H_2O | 4 | -4 | ([H2O])^(-4) SiCl_4 | 1 | -1 | ([SiCl4])^(-1) HCl | 4 | 4 | ([HCl])^4 H_4O_4Si_1 | 1 | 1 | [H4O4Si1] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([H2O])^(-4) ([SiCl4])^(-1) ([HCl])^4 [H4O4Si1] = (([HCl])^4 [H4O4Si1])/(([H2O])^4 [SiCl4])

Construct the rate of reaction expression for: H_2O + SiCl_4 ⟶ HCl + H_4O_4Si_1 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 4 H_2O + SiCl_4 ⟶ 4 HCl + H_4O_4Si_1 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i H_2O | 4 | -4 SiCl_4 | 1 | -1 HCl | 4 | 4 H_4O_4Si_1 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term H_2O | 4 | -4 | -1/4 (Δ[H2O])/(Δt) SiCl_4 | 1 | -1 | -(Δ[SiCl4])/(Δt) HCl | 4 | 4 | 1/4 (Δ[HCl])/(Δt) H_4O_4Si_1 | 1 | 1 | (Δ[H4O4Si1])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/4 (Δ[H2O])/(Δt) = -(Δ[SiCl4])/(Δt) = 1/4 (Δ[HCl])/(Δt) = (Δ[H4O4Si1])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| water | silicon tetrachloride | hydrogen chloride | orthosilicic acid formula | H_2O | SiCl_4 | HCl | H_4O_4Si_1 Hill formula | H_2O | Cl_4Si | ClH | H_4O_4Si name | water | silicon tetrachloride | hydrogen chloride | orthosilicic acid IUPAC name | water | tetrachlorosilane | hydrogen chloride | silicic acid

| water | silicon tetrachloride | hydrogen chloride | orthosilicic acid molar mass | 18.015 g/mol | 169.9 g/mol | 36.46 g/mol | 96.11 g/mol phase | liquid (at STP) | liquid (at STP) | gas (at STP) | melting point | 0 °C | -70 °C | -114.17 °C | boiling point | 99.9839 °C | 57.6 °C | -85 °C | density | 1 g/cm^3 | 1.483 g/cm^3 | 0.00149 g/cm^3 (at 25 °C) | solubility in water | | decomposes | miscible | surface tension | 0.0728 N/m | 0.0196 N/m | | dynamic viscosity | 8.9×10^-4 Pa s (at 25 °C) | 0.0994 Pa s (at 25 °C) | | odor | odorless | | |