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NaOH + H2O2 + SnS = H2O + Na2SO4 + Na2SnO3

Input interpretation

NaOH sodium hydroxide + H_2O_2 hydrogen peroxide + SnS tin(II) sulfide ⟶ H_2O water + Na_2SO_4 sodium sulfate + Na_2SnO_3 sodium stannate
NaOH sodium hydroxide + H_2O_2 hydrogen peroxide + SnS tin(II) sulfide ⟶ H_2O water + Na_2SO_4 sodium sulfate + Na_2SnO_3 sodium stannate

Balanced equation

Balance the chemical equation algebraically: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 NaOH + c_2 H_2O_2 + c_3 SnS ⟶ c_4 H_2O + c_5 Na_2SO_4 + c_6 Na_2SnO_3 Set the number of atoms in the reactants equal to the number of atoms in the products for H, Na, O, S and Sn: H: | c_1 + 2 c_2 = 2 c_4 Na: | c_1 = 2 c_5 + 2 c_6 O: | c_1 + 2 c_2 = c_4 + 4 c_5 + 3 c_6 S: | c_3 = c_5 Sn: | c_3 = c_6 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_3 = 1 and solve the system of equations for the remaining coefficients: c_1 = 4 c_2 = 5 c_3 = 1 c_4 = 7 c_5 = 1 c_6 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: |   | 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3
Balance the chemical equation algebraically: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 NaOH + c_2 H_2O_2 + c_3 SnS ⟶ c_4 H_2O + c_5 Na_2SO_4 + c_6 Na_2SnO_3 Set the number of atoms in the reactants equal to the number of atoms in the products for H, Na, O, S and Sn: H: | c_1 + 2 c_2 = 2 c_4 Na: | c_1 = 2 c_5 + 2 c_6 O: | c_1 + 2 c_2 = c_4 + 4 c_5 + 3 c_6 S: | c_3 = c_5 Sn: | c_3 = c_6 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_3 = 1 and solve the system of equations for the remaining coefficients: c_1 = 4 c_2 = 5 c_3 = 1 c_4 = 7 c_5 = 1 c_6 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3

Structures

 + + ⟶ + +
+ + ⟶ + +

Names

sodium hydroxide + hydrogen peroxide + tin(II) sulfide ⟶ water + sodium sulfate + sodium stannate
sodium hydroxide + hydrogen peroxide + tin(II) sulfide ⟶ water + sodium sulfate + sodium stannate

Equilibrium constant

Construct the equilibrium constant, K, expression for: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i NaOH | 4 | -4 H_2O_2 | 5 | -5 SnS | 1 | -1 H_2O | 7 | 7 Na_2SO_4 | 1 | 1 Na_2SnO_3 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression NaOH | 4 | -4 | ([NaOH])^(-4) H_2O_2 | 5 | -5 | ([H2O2])^(-5) SnS | 1 | -1 | ([SnS])^(-1) H_2O | 7 | 7 | ([H2O])^7 Na_2SO_4 | 1 | 1 | [Na2SO4] Na_2SnO_3 | 1 | 1 | [Na2SnO3] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: |   | K_c = ([NaOH])^(-4) ([H2O2])^(-5) ([SnS])^(-1) ([H2O])^7 [Na2SO4] [Na2SnO3] = (([H2O])^7 [Na2SO4] [Na2SnO3])/(([NaOH])^4 ([H2O2])^5 [SnS])
Construct the equilibrium constant, K, expression for: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i NaOH | 4 | -4 H_2O_2 | 5 | -5 SnS | 1 | -1 H_2O | 7 | 7 Na_2SO_4 | 1 | 1 Na_2SnO_3 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression NaOH | 4 | -4 | ([NaOH])^(-4) H_2O_2 | 5 | -5 | ([H2O2])^(-5) SnS | 1 | -1 | ([SnS])^(-1) H_2O | 7 | 7 | ([H2O])^7 Na_2SO_4 | 1 | 1 | [Na2SO4] Na_2SnO_3 | 1 | 1 | [Na2SnO3] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([NaOH])^(-4) ([H2O2])^(-5) ([SnS])^(-1) ([H2O])^7 [Na2SO4] [Na2SnO3] = (([H2O])^7 [Na2SO4] [Na2SnO3])/(([NaOH])^4 ([H2O2])^5 [SnS])

Rate of reaction

Construct the rate of reaction expression for: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i NaOH | 4 | -4 H_2O_2 | 5 | -5 SnS | 1 | -1 H_2O | 7 | 7 Na_2SO_4 | 1 | 1 Na_2SnO_3 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term NaOH | 4 | -4 | -1/4 (Δ[NaOH])/(Δt) H_2O_2 | 5 | -5 | -1/5 (Δ[H2O2])/(Δt) SnS | 1 | -1 | -(Δ[SnS])/(Δt) H_2O | 7 | 7 | 1/7 (Δ[H2O])/(Δt) Na_2SO_4 | 1 | 1 | (Δ[Na2SO4])/(Δt) Na_2SnO_3 | 1 | 1 | (Δ[Na2SnO3])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: |   | rate = -1/4 (Δ[NaOH])/(Δt) = -1/5 (Δ[H2O2])/(Δt) = -(Δ[SnS])/(Δt) = 1/7 (Δ[H2O])/(Δt) = (Δ[Na2SO4])/(Δt) = (Δ[Na2SnO3])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)
Construct the rate of reaction expression for: NaOH + H_2O_2 + SnS ⟶ H_2O + Na_2SO_4 + Na_2SnO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 4 NaOH + 5 H_2O_2 + SnS ⟶ 7 H_2O + Na_2SO_4 + Na_2SnO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i NaOH | 4 | -4 H_2O_2 | 5 | -5 SnS | 1 | -1 H_2O | 7 | 7 Na_2SO_4 | 1 | 1 Na_2SnO_3 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term NaOH | 4 | -4 | -1/4 (Δ[NaOH])/(Δt) H_2O_2 | 5 | -5 | -1/5 (Δ[H2O2])/(Δt) SnS | 1 | -1 | -(Δ[SnS])/(Δt) H_2O | 7 | 7 | 1/7 (Δ[H2O])/(Δt) Na_2SO_4 | 1 | 1 | (Δ[Na2SO4])/(Δt) Na_2SnO_3 | 1 | 1 | (Δ[Na2SnO3])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/4 (Δ[NaOH])/(Δt) = -1/5 (Δ[H2O2])/(Δt) = -(Δ[SnS])/(Δt) = 1/7 (Δ[H2O])/(Δt) = (Δ[Na2SO4])/(Δt) = (Δ[Na2SnO3])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

Chemical names and formulas

 | sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate formula | NaOH | H_2O_2 | SnS | H_2O | Na_2SO_4 | Na_2SnO_3 Hill formula | HNaO | H_2O_2 | SSn | H_2O | Na_2O_4S | Na_2O_3Sn name | sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate IUPAC name | sodium hydroxide | hydrogen peroxide | thioxotin | water | disodium sulfate | disodium dioxido-oxo-tin
| sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate formula | NaOH | H_2O_2 | SnS | H_2O | Na_2SO_4 | Na_2SnO_3 Hill formula | HNaO | H_2O_2 | SSn | H_2O | Na_2O_4S | Na_2O_3Sn name | sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate IUPAC name | sodium hydroxide | hydrogen peroxide | thioxotin | water | disodium sulfate | disodium dioxido-oxo-tin

Substance properties

 | sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate molar mass | 39.997 g/mol | 34.014 g/mol | 150.77 g/mol | 18.015 g/mol | 142.04 g/mol | 212.687 g/mol phase | solid (at STP) | liquid (at STP) | | liquid (at STP) | solid (at STP) |  melting point | 323 °C | -0.43 °C | | 0 °C | 884 °C |  boiling point | 1390 °C | 150.2 °C | | 99.9839 °C | 1429 °C |  density | 2.13 g/cm^3 | 1.44 g/cm^3 | 5.22 g/cm^3 | 1 g/cm^3 | 2.68 g/cm^3 | 4.68 g/cm^3 solubility in water | soluble | miscible | | | soluble |  surface tension | 0.07435 N/m | 0.0804 N/m | | 0.0728 N/m | |  dynamic viscosity | 0.004 Pa s (at 350 °C) | 0.001249 Pa s (at 20 °C) | | 8.9×10^-4 Pa s (at 25 °C) | |  odor | | | | odorless | |
| sodium hydroxide | hydrogen peroxide | tin(II) sulfide | water | sodium sulfate | sodium stannate molar mass | 39.997 g/mol | 34.014 g/mol | 150.77 g/mol | 18.015 g/mol | 142.04 g/mol | 212.687 g/mol phase | solid (at STP) | liquid (at STP) | | liquid (at STP) | solid (at STP) | melting point | 323 °C | -0.43 °C | | 0 °C | 884 °C | boiling point | 1390 °C | 150.2 °C | | 99.9839 °C | 1429 °C | density | 2.13 g/cm^3 | 1.44 g/cm^3 | 5.22 g/cm^3 | 1 g/cm^3 | 2.68 g/cm^3 | 4.68 g/cm^3 solubility in water | soluble | miscible | | | soluble | surface tension | 0.07435 N/m | 0.0804 N/m | | 0.0728 N/m | | dynamic viscosity | 0.004 Pa s (at 350 °C) | 0.001249 Pa s (at 20 °C) | | 8.9×10^-4 Pa s (at 25 °C) | | odor | | | | odorless | |

Units