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silicon tetraiodide

Input interpretation

silicon tetraiodide
silicon tetraiodide

Chemical names and formulas

formula | SiI_4 Hill formula | I_4Si name | silicon tetraiodide IUPAC name | tetraiodosilane alternate names | silane, tetraiodo- | silicon iodide | silicon(IV) iodide | tetraiodosilane mass fractions | I (iodine) 94.8% | Si (silicon) 5.24%
formula | SiI_4 Hill formula | I_4Si name | silicon tetraiodide IUPAC name | tetraiodosilane alternate names | silane, tetraiodo- | silicon iodide | silicon(IV) iodide | tetraiodosilane mass fractions | I (iodine) 94.8% | Si (silicon) 5.24%

Lewis structure

Draw the Lewis structure of silicon tetraiodide. Start by drawing the overall structure of the molecule:  Count the total valence electrons of the iodine (n_I, val = 7) and silicon (n_Si, val = 4) atoms: 4 n_I, val + n_Si, val = 32 Calculate the number of electrons needed to completely fill the valence shells for iodine (n_I, full = 8) and silicon (n_Si, full = 8): 4 n_I, full + n_Si, full = 40 Subtracting these two numbers shows that 40 - 32 = 8 bonding electrons are needed. Each bond has two electrons, so the above diagram has all the necessary bonds. There are 4 bonds and hence 8 bonding electrons in the diagram. Lastly, fill in the remaining unbonded electrons on each atom. In total, there remain 32 - 8 = 24 electrons left to draw: Answer: |   |
Draw the Lewis structure of silicon tetraiodide. Start by drawing the overall structure of the molecule: Count the total valence electrons of the iodine (n_I, val = 7) and silicon (n_Si, val = 4) atoms: 4 n_I, val + n_Si, val = 32 Calculate the number of electrons needed to completely fill the valence shells for iodine (n_I, full = 8) and silicon (n_Si, full = 8): 4 n_I, full + n_Si, full = 40 Subtracting these two numbers shows that 40 - 32 = 8 bonding electrons are needed. Each bond has two electrons, so the above diagram has all the necessary bonds. There are 4 bonds and hence 8 bonding electrons in the diagram. Lastly, fill in the remaining unbonded electrons on each atom. In total, there remain 32 - 8 = 24 electrons left to draw: Answer: | |

3D structure

3D structure
3D structure

Basic properties

molar mass | 535.703 g/mol phase | solid (at STP) melting point | 120.5 °C boiling point | 287.4 °C density | 4.198 g/cm^3 solubility in water | insoluble
molar mass | 535.703 g/mol phase | solid (at STP) melting point | 120.5 °C boiling point | 287.4 °C density | 4.198 g/cm^3 solubility in water | insoluble

Units

Solid properties (at STP)

density | 4.198 g/cm^3 vapor pressure | 0.0043 mmHg (at 25 °C)
density | 4.198 g/cm^3 vapor pressure | 0.0043 mmHg (at 25 °C)

Units

Thermodynamic properties

specific heat of formation Δ_fH° | solid | -0.3537 kJ/g molar heat of formation Δ_fH° | solid | -189.5 kJ/mol molar heat of vaporization | 52 kJ/mol |  specific heat of vaporization | 0.0971 kJ/g |  molar heat of fusion | 19.7 kJ/mol |  specific heat of fusion | 0.0368 kJ/g |  critical temperature | 944 K |  (at STP)
specific heat of formation Δ_fH° | solid | -0.3537 kJ/g molar heat of formation Δ_fH° | solid | -189.5 kJ/mol molar heat of vaporization | 52 kJ/mol | specific heat of vaporization | 0.0971 kJ/g | molar heat of fusion | 19.7 kJ/mol | specific heat of fusion | 0.0368 kJ/g | critical temperature | 944 K | (at STP)

Chemical identifiers

CAS number | 13465-84-4 PubChem CID number | 83498 PubChem SID number | 24870305 SMILES identifier | [Si](I)(I)(I)I InChI identifier | InChI=1/I4Si/c1-5(2, 3)4 MDL number | MFCD00054041
CAS number | 13465-84-4 PubChem CID number | 83498 PubChem SID number | 24870305 SMILES identifier | [Si](I)(I)(I)I InChI identifier | InChI=1/I4Si/c1-5(2, 3)4 MDL number | MFCD00054041

Safety properties

flash point | -18 °C
flash point | -18 °C
DOT hazard class | 8 DOT numbers | 3260
DOT hazard class | 8 DOT numbers | 3260