O2 + P = P2O2

O_2 oxygen + P red phosphorus ⟶ P2O2

Balance the chemical equation algebraically: O_2 + P ⟶ P2O2 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 O_2 + c_2 P ⟶ c_3 P2O2 Set the number of atoms in the reactants equal to the number of atoms in the products for O and P: O: | 2 c_1 = 2 c_3 P: | c_2 = 2 c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 2 c_3 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | O_2 + 2 P ⟶ P2O2

+ ⟶ P2O2

oxygen + red phosphorus ⟶ P2O2

Construct the equilibrium constant, K, expression for: O_2 + P ⟶ P2O2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: O_2 + 2 P ⟶ P2O2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 1 | -1 P | 2 | -2 P2O2 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression O_2 | 1 | -1 | ([O2])^(-1) P | 2 | -2 | ([P])^(-2) P2O2 | 1 | 1 | [P2O2] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([O2])^(-1) ([P])^(-2) [P2O2] = ([P2O2])/([O2] ([P])^2)

Construct the rate of reaction expression for: O_2 + P ⟶ P2O2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: O_2 + 2 P ⟶ P2O2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 1 | -1 P | 2 | -2 P2O2 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term O_2 | 1 | -1 | -(Δ[O2])/(Δt) P | 2 | -2 | -1/2 (Δ[P])/(Δt) P2O2 | 1 | 1 | (Δ[P2O2])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[O2])/(Δt) = -1/2 (Δ[P])/(Δt) = (Δ[P2O2])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| oxygen | red phosphorus | P2O2 formula | O_2 | P | P2O2 Hill formula | O_2 | P | O2P2 name | oxygen | red phosphorus | IUPAC name | molecular oxygen | phosphorus |

| oxygen | red phosphorus | P2O2 molar mass | 31.998 g/mol | 30.973761998 g/mol | 93.946 g/mol phase | gas (at STP) | solid (at STP) | melting point | -218 °C | 579.2 °C | boiling point | -183 °C | | density | 0.001429 g/cm^3 (at 0 °C) | 2.16 g/cm^3 | solubility in water | | insoluble | surface tension | 0.01347 N/m | | dynamic viscosity | 2.055×10^-5 Pa s (at 25 °C) | 7.6×10^-4 Pa s (at 20.2 °C) | odor | odorless | |