KOH + SO2 = H2O + K2SO3

KOH (potassium hydroxide) + SO_2 (sulfur dioxide) ⟶ H_2O (water) + K_2SO_3 (potassium sulfite)

Balance the chemical equation algebraically: KOH + SO_2 ⟶ H_2O + K_2SO_3 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 KOH + c_2 SO_2 ⟶ c_3 H_2O + c_4 K_2SO_3 Set the number of atoms in the reactants equal to the number of atoms in the products for H, K, O and S: H: | c_1 = 2 c_3 K: | c_1 = 2 c_4 O: | c_1 + 2 c_2 = c_3 + 3 c_4 S: | c_2 = c_4 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_2 = 1 and solve the system of equations for the remaining coefficients: c_1 = 2 c_2 = 1 c_3 = 1 c_4 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 2 KOH + SO_2 ⟶ H_2O + K_2SO_3

+ ⟶ +

potassium hydroxide + sulfur dioxide ⟶ water + potassium sulfite

Construct the equilibrium constant, K, expression for: KOH + SO_2 ⟶ H_2O + K_2SO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 2 KOH + SO_2 ⟶ H_2O + K_2SO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i KOH | 2 | -2 SO_2 | 1 | -1 H_2O | 1 | 1 K_2SO_3 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression KOH | 2 | -2 | ([KOH])^(-2) SO_2 | 1 | -1 | ([SO2])^(-1) H_2O | 1 | 1 | [H2O] K_2SO_3 | 1 | 1 | [K2SO3] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([KOH])^(-2) ([SO2])^(-1) [H2O] [K2SO3] = ([H2O] [K2SO3])/(([KOH])^2 [SO2])

Construct the rate of reaction expression for: KOH + SO_2 ⟶ H_2O + K_2SO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 2 KOH + SO_2 ⟶ H_2O + K_2SO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i KOH | 2 | -2 SO_2 | 1 | -1 H_2O | 1 | 1 K_2SO_3 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term KOH | 2 | -2 | -1/2 (Δ[KOH])/(Δt) SO_2 | 1 | -1 | -(Δ[SO2])/(Δt) H_2O | 1 | 1 | (Δ[H2O])/(Δt) K_2SO_3 | 1 | 1 | (Δ[K2SO3])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/2 (Δ[KOH])/(Δt) = -(Δ[SO2])/(Δt) = (Δ[H2O])/(Δt) = (Δ[K2SO3])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| potassium hydroxide | sulfur dioxide | water | potassium sulfite formula | KOH | SO_2 | H_2O | K_2SO_3 Hill formula | HKO | O_2S | H_2O | K_2O_3S name | potassium hydroxide | sulfur dioxide | water | potassium sulfite IUPAC name | potassium hydroxide | sulfur dioxide | water | dipotassium sulfite