FeCO3 = CO2 + FeO

FeCO_3 iron(II) carbonate ⟶ CO_2 carbon dioxide + FeO iron(II) oxide

Balance the chemical equation algebraically: FeCO_3 ⟶ CO_2 + FeO Add stoichiometric coefficients, c_i, to the reactants and products: c_1 FeCO_3 ⟶ c_2 CO_2 + c_3 FeO Set the number of atoms in the reactants equal to the number of atoms in the products for C, Fe and O: C: | c_1 = c_2 Fe: | c_1 = c_3 O: | 3 c_1 = 2 c_2 + c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 c_3 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | FeCO_3 ⟶ CO_2 + FeO

⟶ +

iron(II) carbonate ⟶ carbon dioxide + iron(II) oxide

Construct the equilibrium constant, K, expression for: FeCO_3 ⟶ CO_2 + FeO Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: FeCO_3 ⟶ CO_2 + FeO Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i FeCO_3 | 1 | -1 CO_2 | 1 | 1 FeO | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression FeCO_3 | 1 | -1 | ([FeCO3])^(-1) CO_2 | 1 | 1 | [CO2] FeO | 1 | 1 | [FeO] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([FeCO3])^(-1) [CO2] [FeO] = ([CO2] [FeO])/([FeCO3])

Construct the rate of reaction expression for: FeCO_3 ⟶ CO_2 + FeO Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: FeCO_3 ⟶ CO_2 + FeO Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i FeCO_3 | 1 | -1 CO_2 | 1 | 1 FeO | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term FeCO_3 | 1 | -1 | -(Δ[FeCO3])/(Δt) CO_2 | 1 | 1 | (Δ[CO2])/(Δt) FeO | 1 | 1 | (Δ[FeO])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[FeCO3])/(Δt) = (Δ[CO2])/(Δt) = (Δ[FeO])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| iron(II) carbonate | carbon dioxide | iron(II) oxide formula | FeCO_3 | CO_2 | FeO Hill formula | CFeO_3 | CO_2 | FeO name | iron(II) carbonate | carbon dioxide | iron(II) oxide IUPAC name | ferrous carbonate | carbon dioxide | oxoiron

| iron(II) carbonate | carbon dioxide | iron(II) oxide molar mass | 115.85 g/mol | 44.009 g/mol | 71.844 g/mol phase | | gas (at STP) | solid (at STP) melting point | | -56.56 °C (at triple point) | 1360 °C boiling point | | -78.5 °C (at sublimation point) | density | | 0.00184212 g/cm^3 (at 20 °C) | 5.7 g/cm^3 solubility in water | | | insoluble dynamic viscosity | | 1.491×10^-5 Pa s (at 25 °C) | odor | | odorless |