Ca + HBr = H2 + CaBr

Ca calcium + HBr hydrogen bromide ⟶ H_2 hydrogen + CaBr

Balance the chemical equation algebraically: Ca + HBr ⟶ H_2 + CaBr Add stoichiometric coefficients, c_i, to the reactants and products: c_1 Ca + c_2 HBr ⟶ c_3 H_2 + c_4 CaBr Set the number of atoms in the reactants equal to the number of atoms in the products for Ca, Br and H: Ca: | c_1 = c_4 Br: | c_2 = c_4 H: | c_2 = 2 c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_3 = 1 and solve the system of equations for the remaining coefficients: c_1 = 2 c_2 = 2 c_3 = 1 c_4 = 2 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 2 Ca + 2 HBr ⟶ H_2 + 2 CaBr

+ ⟶ + CaBr

calcium + hydrogen bromide ⟶ hydrogen + CaBr

Construct the equilibrium constant, K, expression for: Ca + HBr ⟶ H_2 + CaBr Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 2 Ca + 2 HBr ⟶ H_2 + 2 CaBr Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i Ca | 2 | -2 HBr | 2 | -2 H_2 | 1 | 1 CaBr | 2 | 2 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression Ca | 2 | -2 | ([Ca])^(-2) HBr | 2 | -2 | ([HBr])^(-2) H_2 | 1 | 1 | [H2] CaBr | 2 | 2 | ([CaBr])^2 The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([Ca])^(-2) ([HBr])^(-2) [H2] ([CaBr])^2 = ([H2] ([CaBr])^2)/(([Ca])^2 ([HBr])^2)

Construct the rate of reaction expression for: Ca + HBr ⟶ H_2 + CaBr Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 2 Ca + 2 HBr ⟶ H_2 + 2 CaBr Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i Ca | 2 | -2 HBr | 2 | -2 H_2 | 1 | 1 CaBr | 2 | 2 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term Ca | 2 | -2 | -1/2 (Δ[Ca])/(Δt) HBr | 2 | -2 | -1/2 (Δ[HBr])/(Δt) H_2 | 1 | 1 | (Δ[H2])/(Δt) CaBr | 2 | 2 | 1/2 (Δ[CaBr])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/2 (Δ[Ca])/(Δt) = -1/2 (Δ[HBr])/(Δt) = (Δ[H2])/(Δt) = 1/2 (Δ[CaBr])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| calcium | hydrogen bromide | hydrogen | CaBr formula | Ca | HBr | H_2 | CaBr Hill formula | Ca | BrH | H_2 | BrCa name | calcium | hydrogen bromide | hydrogen | IUPAC name | calcium | hydrogen bromide | molecular hydrogen |

| calcium | hydrogen bromide | hydrogen | CaBr molar mass | 40.078 g/mol | 80.912 g/mol | 2.016 g/mol | 119.98 g/mol phase | solid (at STP) | gas (at STP) | gas (at STP) | melting point | 850 °C | -86.8 °C | -259.2 °C | boiling point | 1484 °C | -66.38 °C | -252.8 °C | density | 1.54 g/cm^3 | 0.003307 g/cm^3 (at 25 °C) | 8.99×10^-5 g/cm^3 (at 0 °C) | solubility in water | decomposes | miscible | | surface tension | | 0.0271 N/m | | dynamic viscosity | | 8.4×10^-4 Pa s (at -75 °C) | 8.9×10^-6 Pa s (at 25 °C) | odor | | | odorless |