O2 + Mg = MgO2

O_2 (oxygen) + Mg (magnesium) ⟶ MgO_2 (magnesium peroxide)

Balance the chemical equation algebraically: O_2 + Mg ⟶ MgO_2 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 O_2 + c_2 Mg ⟶ c_3 MgO_2 Set the number of atoms in the reactants equal to the number of atoms in the products for O and Mg: O: | 2 c_1 = 2 c_3 Mg: | c_2 = c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 c_3 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | O_2 + Mg ⟶ MgO_2

+ ⟶

oxygen + magnesium ⟶ magnesium peroxide

Construct the equilibrium constant, K, expression for: O_2 + Mg ⟶ MgO_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: O_2 + Mg ⟶ MgO_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 1 | -1 Mg | 1 | -1 MgO_2 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression O_2 | 1 | -1 | ([O2])^(-1) Mg | 1 | -1 | ([Mg])^(-1) MgO_2 | 1 | 1 | [MgO2] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([O2])^(-1) ([Mg])^(-1) [MgO2] = ([MgO2])/([O2] [Mg])

Construct the rate of reaction expression for: O_2 + Mg ⟶ MgO_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: O_2 + Mg ⟶ MgO_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 1 | -1 Mg | 1 | -1 MgO_2 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term O_2 | 1 | -1 | -(Δ[O2])/(Δt) Mg | 1 | -1 | -(Δ[Mg])/(Δt) MgO_2 | 1 | 1 | (Δ[MgO2])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[O2])/(Δt) = -(Δ[Mg])/(Δt) = (Δ[MgO2])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| oxygen | magnesium | magnesium peroxide formula | O_2 | Mg | MgO_2 name | oxygen | magnesium | magnesium peroxide IUPAC name | molecular oxygen | magnesium | magnesium peroxide

| oxygen | magnesium | magnesium peroxide molar mass | 31.998 g/mol | 24.305 g/mol | 56.303 g/mol phase | gas (at STP) | solid (at STP) | solid (at STP) melting point | -218 °C | 648 °C | 223 °C boiling point | -183 °C | 1090 °C | density | 0.001429 g/cm^3 (at 0 °C) | 1.738 g/cm^3 | 3 g/cm^3 solubility in water | | reacts | insoluble surface tension | 0.01347 N/m | | dynamic viscosity | 2.055×10^-5 Pa s (at 25 °C) | | odor | odorless | |