H2O + SO2 + KIO3 = H2SO4 + K2SO4 + I2

H_2O (water) + SO_2 (sulfur dioxide) + KIO_3 (potassium iodate) ⟶ H_2SO_4 (sulfuric acid) + K_2SO_4 (potassium sulfate) + I_2 (iodine)

Balance the chemical equation algebraically: H_2O + SO_2 + KIO_3 ⟶ H_2SO_4 + K_2SO_4 + I_2 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 H_2O + c_2 SO_2 + c_3 KIO_3 ⟶ c_4 H_2SO_4 + c_5 K_2SO_4 + c_6 I_2 Set the number of atoms in the reactants equal to the number of atoms in the products for H, O, S, I and K: H: | 2 c_1 = 2 c_4 O: | c_1 + 2 c_2 + 3 c_3 = 4 c_4 + 4 c_5 S: | c_2 = c_4 + c_5 I: | c_3 = 2 c_6 K: | c_3 = 2 c_5 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_5 = 1 and solve the system of equations for the remaining coefficients: c_1 = 4 c_2 = 5 c_3 = 2 c_4 = 4 c_5 = 1 c_6 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 4 H_2O + 5 SO_2 + 2 KIO_3 ⟶ 4 H_2SO_4 + K_2SO_4 + I_2

+ + ⟶ + +

water + sulfur dioxide + potassium iodate ⟶ sulfuric acid + potassium sulfate + iodine

Construct the equilibrium constant, K, expression for: H_2O + SO_2 + KIO_3 ⟶ H_2SO_4 + K_2SO_4 + I_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 4 H_2O + 5 SO_2 + 2 KIO_3 ⟶ 4 H_2SO_4 + K_2SO_4 + I_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i H_2O | 4 | -4 SO_2 | 5 | -5 KIO_3 | 2 | -2 H_2SO_4 | 4 | 4 K_2SO_4 | 1 | 1 I_2 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression H_2O | 4 | -4 | ([H2O])^(-4) SO_2 | 5 | -5 | ([SO2])^(-5) KIO_3 | 2 | -2 | ([KIO3])^(-2) H_2SO_4 | 4 | 4 | ([H2SO4])^4 K_2SO_4 | 1 | 1 | [K2SO4] I_2 | 1 | 1 | [I2] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([H2O])^(-4) ([SO2])^(-5) ([KIO3])^(-2) ([H2SO4])^4 [K2SO4] [I2] = (([H2SO4])^4 [K2SO4] [I2])/(([H2O])^4 ([SO2])^5 ([KIO3])^2)

Construct the rate of reaction expression for: H_2O + SO_2 + KIO_3 ⟶ H_2SO_4 + K_2SO_4 + I_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 4 H_2O + 5 SO_2 + 2 KIO_3 ⟶ 4 H_2SO_4 + K_2SO_4 + I_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i H_2O | 4 | -4 SO_2 | 5 | -5 KIO_3 | 2 | -2 H_2SO_4 | 4 | 4 K_2SO_4 | 1 | 1 I_2 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term H_2O | 4 | -4 | -1/4 (Δ[H2O])/(Δt) SO_2 | 5 | -5 | -1/5 (Δ[SO2])/(Δt) KIO_3 | 2 | -2 | -1/2 (Δ[KIO3])/(Δt) H_2SO_4 | 4 | 4 | 1/4 (Δ[H2SO4])/(Δt) K_2SO_4 | 1 | 1 | (Δ[K2SO4])/(Δt) I_2 | 1 | 1 | (Δ[I2])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/4 (Δ[H2O])/(Δt) = -1/5 (Δ[SO2])/(Δt) = -1/2 (Δ[KIO3])/(Δt) = 1/4 (Δ[H2SO4])/(Δt) = (Δ[K2SO4])/(Δt) = (Δ[I2])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| water | sulfur dioxide | potassium iodate | sulfuric acid | potassium sulfate | iodine formula | H_2O | SO_2 | KIO_3 | H_2SO_4 | K_2SO_4 | I_2 Hill formula | H_2O | O_2S | IKO_3 | H_2O_4S | K_2O_4S | I_2 name | water | sulfur dioxide | potassium iodate | sulfuric acid | potassium sulfate | iodine IUPAC name | water | sulfur dioxide | potassium iodate | sulfuric acid | dipotassium sulfate | molecular iodine