Input interpretation
![N, N-dimethylformamide](../image_source/cb568cae3d9fc6f7910ec1905d6b98fd.png)
N, N-dimethylformamide
Chemical names and formulas
![formula | HCON(CH_3)_2 Hill formula | C_3H_7NO name | N, N-dimethylformamide alternate names | dimethylformamide | DMF | N-formyldimethylamine | N, N-dimethylmethanamide mass fractions | C (carbon) 49.3% | H (hydrogen) 9.65% | N (nitrogen) 19.2% | O (oxygen) 21.9%](../image_source/774964cb5c7e40516364cd6a211192ec.png)
formula | HCON(CH_3)_2 Hill formula | C_3H_7NO name | N, N-dimethylformamide alternate names | dimethylformamide | DMF | N-formyldimethylamine | N, N-dimethylmethanamide mass fractions | C (carbon) 49.3% | H (hydrogen) 9.65% | N (nitrogen) 19.2% | O (oxygen) 21.9%
Lewis structure
![Draw the Lewis structure of N, N-dimethylformamide. Start by drawing the overall structure of the molecule, ignoring potential double and triple bonds: Count the total valence electrons of the carbon (n_C, val = 4), hydrogen (n_H, val = 1), nitrogen (n_N, val = 5), and oxygen (n_O, val = 6) atoms: 3 n_C, val + 7 n_H, val + n_N, val + n_O, val = 30 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), hydrogen (n_H, full = 2), nitrogen (n_N, full = 8), and oxygen (n_O, full = 8): 3 n_C, full + 7 n_H, full + n_N, full + n_O, full = 54 Subtracting these two numbers shows that 54 - 30 = 24 bonding electrons are needed. Each bond has two electrons, so in addition to the 11 bonds already present in the diagram add 1 bond. To minimize formal charge oxygen wants 2 bonds and carbon wants 4 bonds. Identify the atoms that want additional bonds and the number of electrons remaining on each atom: Fill in the 1 bond by pairing electrons between adjacent highlighted atoms: Answer: | |](../image_source/50eb64bf42fe46b48f2e8fa89bbea5ad.png)
Draw the Lewis structure of N, N-dimethylformamide. Start by drawing the overall structure of the molecule, ignoring potential double and triple bonds: Count the total valence electrons of the carbon (n_C, val = 4), hydrogen (n_H, val = 1), nitrogen (n_N, val = 5), and oxygen (n_O, val = 6) atoms: 3 n_C, val + 7 n_H, val + n_N, val + n_O, val = 30 Calculate the number of electrons needed to completely fill the valence shells for carbon (n_C, full = 8), hydrogen (n_H, full = 2), nitrogen (n_N, full = 8), and oxygen (n_O, full = 8): 3 n_C, full + 7 n_H, full + n_N, full + n_O, full = 54 Subtracting these two numbers shows that 54 - 30 = 24 bonding electrons are needed. Each bond has two electrons, so in addition to the 11 bonds already present in the diagram add 1 bond. To minimize formal charge oxygen wants 2 bonds and carbon wants 4 bonds. Identify the atoms that want additional bonds and the number of electrons remaining on each atom: Fill in the 1 bond by pairing electrons between adjacent highlighted atoms: Answer: | |
3D structure
![3D structure](../image_source/b8e7becb280eaac01bdc89f8d8991b24.png)
3D structure
Basic properties
![molar mass | 73.1 g/mol phase | liquid (at STP) melting point | -61 °C boiling point | 153 °C density | 0.944 g/cm^3 solubility in water | miscible dielectric constant | 38.25](../image_source/3284ee7a60f9108561b73c2b2e6acc57.png)
molar mass | 73.1 g/mol phase | liquid (at STP) melting point | -61 °C boiling point | 153 °C density | 0.944 g/cm^3 solubility in water | miscible dielectric constant | 38.25
Hydrophobicity and permeability properties
![experimental LogP hydrophobicity | -1.01 predicted LogP hydrophobicity | -0.77 predicted LogS | 1](../image_source/6cf7968abe01a9d02d798a2934931d75.png)
experimental LogP hydrophobicity | -1.01 predicted LogP hydrophobicity | -0.77 predicted LogS | 1
Basic drug properties
![approval status | experimental | small molecule](../image_source/c7983e520be21e9646c903ee2815c750.png)
approval status | experimental | small molecule
Liquid properties (at STP)
![density | 0.944 g/cm^3 vapor pressure | 2.7 mmHg dynamic viscosity | 7.94×10^-4 Pa s (at 25 °C) surface tension | 0.0352 N/m refractive index | 1.43 UV cutoff wavelength | 270 nm](../image_source/b6830f572d4e742b97887b3ede69beab.png)
density | 0.944 g/cm^3 vapor pressure | 2.7 mmHg dynamic viscosity | 7.94×10^-4 Pa s (at 25 °C) surface tension | 0.0352 N/m refractive index | 1.43 UV cutoff wavelength | 270 nm
Units
Thermodynamic properties
![specific heat capacity c_p | liquid | 2.06 J/(g K) specific heat of formation Δ_fH° | gas | -2.632 kJ/g specific heat of vaporization | 0.643 kJ/g | specific heat of combustion | 26.2 kJ/g | specific heat of fusion | 0.11 kJ/g | critical temperature | 647 K | critical pressure | 4.48 MPa | (at STP)](../image_source/d07c6ac8f1f57600a80204e4ff3a9540.png)
specific heat capacity c_p | liquid | 2.06 J/(g K) specific heat of formation Δ_fH° | gas | -2.632 kJ/g specific heat of vaporization | 0.643 kJ/g | specific heat of combustion | 26.2 kJ/g | specific heat of fusion | 0.11 kJ/g | critical temperature | 647 K | critical pressure | 4.48 MPa | (at STP)
Units
Chemical identifiers
![CAS number | 68-12-2 Beilstein number | 605365 PubChem CID number | 6228 PubChem SID number | 24853607 SMILES identifier | CN(C)C=O](../image_source/4b36054c6c4b5485ef14cc241e1a4a94.png)
CAS number | 68-12-2 Beilstein number | 605365 PubChem CID number | 6228 PubChem SID number | 24853607 SMILES identifier | CN(C)C=O
NFPA label
![NFPA label](../image_source/fe95dd85f8257442c19acb0cd3f8f8a5.png)
NFPA label
Safety properties
![flash point | 57.78 °C autoignition point | 410 °C lower explosive limit | 2.2% (concentration in air) upper explosive limit | 16% (concentration in air)](../image_source/019264db36fed01a8048ea70e8b91ec2.png)
flash point | 57.78 °C autoignition point | 410 °C lower explosive limit | 2.2% (concentration in air) upper explosive limit | 16% (concentration in air)
Toxicity properties
![lethal dosage | 1410 mg/kg (oral dose for rats) short-term exposure limit | 60 mg/m^3 threshold limit value | 10 ppmv](../image_source/4cf55e7419df0adb143e9ccfa18c0107.png)
lethal dosage | 1410 mg/kg (oral dose for rats) short-term exposure limit | 60 mg/m^3 threshold limit value | 10 ppmv
Units