CuSO4Mg = CuMgSO4

CuSO4Mg ⟶ CuMgSO4

Balance the chemical equation algebraically: CuSO4Mg ⟶ CuMgSO4 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 CuSO4Mg ⟶ c_2 CuMgSO4 Set the number of atoms in the reactants equal to the number of atoms in the products for Cu, S, O and Mg: Cu: | c_1 = c_2 S: | c_1 = c_2 O: | 4 c_1 = 4 c_2 Mg: | c_1 = c_2 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | CuSO4Mg ⟶ CuMgSO4

CuSO4Mg ⟶ CuMgSO4

CuSO4Mg ⟶ CuMgSO4

Construct the equilibrium constant, K, expression for: CuSO4Mg ⟶ CuMgSO4 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: CuSO4Mg ⟶ CuMgSO4 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i CuSO4Mg | 1 | -1 CuMgSO4 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression CuSO4Mg | 1 | -1 | ([CuSO4Mg])^(-1) CuMgSO4 | 1 | 1 | [CuMgSO4] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([CuSO4Mg])^(-1) [CuMgSO4] = ([CuMgSO4])/([CuSO4Mg])

Construct the rate of reaction expression for: CuSO4Mg ⟶ CuMgSO4 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: CuSO4Mg ⟶ CuMgSO4 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i CuSO4Mg | 1 | -1 CuMgSO4 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term CuSO4Mg | 1 | -1 | -(Δ[CuSO4Mg])/(Δt) CuMgSO4 | 1 | 1 | (Δ[CuMgSO4])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[CuSO4Mg])/(Δt) = (Δ[CuMgSO4])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| CuSO4Mg | CuMgSO4 formula | CuSO4Mg | CuMgSO4 Hill formula | CuMgO4S | CuMgO4S

| CuSO4Mg | CuMgSO4 molar mass | 183.91 g/mol | 183.91 g/mol