C2H5Cl = HCl + C2H4

C_2H_5Cl chloroethane ⟶ HCl hydrogen chloride + CH_2=CH_2 ethylene

Balance the chemical equation algebraically: C_2H_5Cl ⟶ HCl + CH_2=CH_2 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 C_2H_5Cl ⟶ c_2 HCl + c_3 CH_2=CH_2 Set the number of atoms in the reactants equal to the number of atoms in the products for C, Cl and H: C: | 2 c_1 = 2 c_3 Cl: | c_1 = c_2 H: | 5 c_1 = c_2 + 4 c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 c_3 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | C_2H_5Cl ⟶ HCl + CH_2=CH_2

⟶ +

chloroethane ⟶ hydrogen chloride + ethylene

Construct the equilibrium constant, K, expression for: C_2H_5Cl ⟶ HCl + CH_2=CH_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: C_2H_5Cl ⟶ HCl + CH_2=CH_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i C_2H_5Cl | 1 | -1 HCl | 1 | 1 CH_2=CH_2 | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression C_2H_5Cl | 1 | -1 | ([C2H5Cl])^(-1) HCl | 1 | 1 | [HCl] CH_2=CH_2 | 1 | 1 | [CH2=CH2] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([C2H5Cl])^(-1) [HCl] [CH2=CH2] = ([HCl] [CH2=CH2])/([C2H5Cl])

Construct the rate of reaction expression for: C_2H_5Cl ⟶ HCl + CH_2=CH_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: C_2H_5Cl ⟶ HCl + CH_2=CH_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i C_2H_5Cl | 1 | -1 HCl | 1 | 1 CH_2=CH_2 | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term C_2H_5Cl | 1 | -1 | -(Δ[C2H5Cl])/(Δt) HCl | 1 | 1 | (Δ[HCl])/(Δt) CH_2=CH_2 | 1 | 1 | (Δ[CH2=CH2])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[C2H5Cl])/(Δt) = (Δ[HCl])/(Δt) = (Δ[CH2=CH2])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| chloroethane | hydrogen chloride | ethylene formula | C_2H_5Cl | HCl | CH_2=CH_2 Hill formula | C_2H_5Cl | ClH | C_2H_4 name | chloroethane | hydrogen chloride | ethylene

| chloroethane | hydrogen chloride | ethylene molar mass | 64.51 g/mol | 36.46 g/mol | 28.054 g/mol phase | | gas (at STP) | gas (at STP) melting point | | -114.17 °C | -169 °C boiling point | | -85 °C | -104 °C density | 0.765 g/cm^3 | 0.00149 g/cm^3 (at 25 °C) | 1.153 g/cm^3 (at 25 °C) solubility in water | | miscible | insoluble surface tension | | | 0.0181 N/m dynamic viscosity | | | 1.034×10^-5 Pa s (at 25 °C)