HNO3 + Tl = H2 + TlNO3

HNO_3 nitric acid + Tl thallium ⟶ H_2 hydrogen + TlNO_3 thallous nitrate

Balance the chemical equation algebraically: HNO_3 + Tl ⟶ H_2 + TlNO_3 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 HNO_3 + c_2 Tl ⟶ c_3 H_2 + c_4 TlNO_3 Set the number of atoms in the reactants equal to the number of atoms in the products for H, N, O and Tl: H: | c_1 = 2 c_3 N: | c_1 = c_4 O: | 3 c_1 = 3 c_4 Tl: | c_2 = c_4 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_3 = 1 and solve the system of equations for the remaining coefficients: c_1 = 2 c_2 = 2 c_3 = 1 c_4 = 2 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 2 HNO_3 + 2 Tl ⟶ H_2 + 2 TlNO_3

+ ⟶ +

nitric acid + thallium ⟶ hydrogen + thallous nitrate

Construct the equilibrium constant, K, expression for: HNO_3 + Tl ⟶ H_2 + TlNO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 2 HNO_3 + 2 Tl ⟶ H_2 + 2 TlNO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i HNO_3 | 2 | -2 Tl | 2 | -2 H_2 | 1 | 1 TlNO_3 | 2 | 2 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression HNO_3 | 2 | -2 | ([HNO3])^(-2) Tl | 2 | -2 | ([Tl])^(-2) H_2 | 1 | 1 | [H2] TlNO_3 | 2 | 2 | ([TlNO3])^2 The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([HNO3])^(-2) ([Tl])^(-2) [H2] ([TlNO3])^2 = ([H2] ([TlNO3])^2)/(([HNO3])^2 ([Tl])^2)

Construct the rate of reaction expression for: HNO_3 + Tl ⟶ H_2 + TlNO_3 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 2 HNO_3 + 2 Tl ⟶ H_2 + 2 TlNO_3 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i HNO_3 | 2 | -2 Tl | 2 | -2 H_2 | 1 | 1 TlNO_3 | 2 | 2 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term HNO_3 | 2 | -2 | -1/2 (Δ[HNO3])/(Δt) Tl | 2 | -2 | -1/2 (Δ[Tl])/(Δt) H_2 | 1 | 1 | (Δ[H2])/(Δt) TlNO_3 | 2 | 2 | 1/2 (Δ[TlNO3])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/2 (Δ[HNO3])/(Δt) = -1/2 (Δ[Tl])/(Δt) = (Δ[H2])/(Δt) = 1/2 (Δ[TlNO3])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| nitric acid | thallium | hydrogen | thallous nitrate formula | HNO_3 | Tl | H_2 | TlNO_3 Hill formula | HNO_3 | Tl | H_2 | NO_3Tl name | nitric acid | thallium | hydrogen | thallous nitrate IUPAC name | nitric acid | thallium | molecular hydrogen | thallium(+1) cation nitrate

| nitric acid | thallium | hydrogen | thallous nitrate molar mass | 63.012 g/mol | 204.38 g/mol | 2.016 g/mol | 266.38 g/mol phase | liquid (at STP) | solid (at STP) | gas (at STP) | solid (at STP) melting point | -41.6 °C | 303 °C | -259.2 °C | 206 °C boiling point | 83 °C | 1457 °C | -252.8 °C | density | 1.5129 g/cm^3 | 11.85 g/cm^3 | 8.99×10^-5 g/cm^3 (at 0 °C) | 1.273 g/cm^3 solubility in water | miscible | insoluble | | dynamic viscosity | 7.6×10^-4 Pa s (at 25 °C) | | 8.9×10^-6 Pa s (at 25 °C) | 0.00367 Pa s (at 225 °C) odor | | | odorless |