O2 + C12H26 = H2O + CO2

O_2 oxygen + CH_3(CH_2)_10CH_3 dodecane ⟶ H_2O water + CO_2 carbon dioxide

Balance the chemical equation algebraically: O_2 + CH_3(CH_2)_10CH_3 ⟶ H_2O + CO_2 Add stoichiometric coefficients, c_i, to the reactants and products: c_1 O_2 + c_2 CH_3(CH_2)_10CH_3 ⟶ c_3 H_2O + c_4 CO_2 Set the number of atoms in the reactants equal to the number of atoms in the products for O, C and H: O: | 2 c_1 = c_3 + 2 c_4 C: | 12 c_2 = c_4 H: | 26 c_2 = 2 c_3 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_2 = 1 and solve the system of equations for the remaining coefficients: c_1 = 37/2 c_2 = 1 c_3 = 13 c_4 = 12 Multiply by the least common denominator, 2, to eliminate fractional coefficients: c_1 = 37 c_2 = 2 c_3 = 26 c_4 = 24 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | 37 O_2 + 2 CH_3(CH_2)_10CH_3 ⟶ 26 H_2O + 24 CO_2

+ ⟶ +

oxygen + dodecane ⟶ water + carbon dioxide

| oxygen | dodecane | water | carbon dioxide molecular enthalpy | 0 kJ/mol | -350.9 kJ/mol | -285.8 kJ/mol | -393.5 kJ/mol total enthalpy | 0 kJ/mol | -701.8 kJ/mol | -7432 kJ/mol | -9444 kJ/mol | H_initial = -701.8 kJ/mol | | H_final = -16876 kJ/mol | ΔH_rxn^0 | -16876 kJ/mol - -701.8 kJ/mol = -16174 kJ/mol (exothermic) | | |

Construct the equilibrium constant, K, expression for: O_2 + CH_3(CH_2)_10CH_3 ⟶ H_2O + CO_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: 37 O_2 + 2 CH_3(CH_2)_10CH_3 ⟶ 26 H_2O + 24 CO_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 37 | -37 CH_3(CH_2)_10CH_3 | 2 | -2 H_2O | 26 | 26 CO_2 | 24 | 24 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression O_2 | 37 | -37 | ([O2])^(-37) CH_3(CH_2)_10CH_3 | 2 | -2 | ([CH3(CH2)10CH3])^(-2) H_2O | 26 | 26 | ([H2O])^26 CO_2 | 24 | 24 | ([CO2])^24 The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([O2])^(-37) ([CH3(CH2)10CH3])^(-2) ([H2O])^26 ([CO2])^24 = (([H2O])^26 ([CO2])^24)/(([O2])^37 ([CH3(CH2)10CH3])^2)

Construct the rate of reaction expression for: O_2 + CH_3(CH_2)_10CH_3 ⟶ H_2O + CO_2 Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: 37 O_2 + 2 CH_3(CH_2)_10CH_3 ⟶ 26 H_2O + 24 CO_2 Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i O_2 | 37 | -37 CH_3(CH_2)_10CH_3 | 2 | -2 H_2O | 26 | 26 CO_2 | 24 | 24 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term O_2 | 37 | -37 | -1/37 (Δ[O2])/(Δt) CH_3(CH_2)_10CH_3 | 2 | -2 | -1/2 (Δ[CH3(CH2)10CH3])/(Δt) H_2O | 26 | 26 | 1/26 (Δ[H2O])/(Δt) CO_2 | 24 | 24 | 1/24 (Δ[CO2])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -1/37 (Δ[O2])/(Δt) = -1/2 (Δ[CH3(CH2)10CH3])/(Δt) = 1/26 (Δ[H2O])/(Δt) = 1/24 (Δ[CO2])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| oxygen | dodecane | water | carbon dioxide formula | O_2 | CH_3(CH_2)_10CH_3 | H_2O | CO_2 Hill formula | O_2 | C_12H_26 | H_2O | CO_2 name | oxygen | dodecane | water | carbon dioxide IUPAC name | molecular oxygen | dodecane | water | carbon dioxide