Cl2 + C6H6 = HCl + C6H5Cl

Cl_2 chlorine + C_6H_6 benzene ⟶ HCl hydrogen chloride + C_6H_5Cl chlorobenzene

Balance the chemical equation algebraically: Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl Add stoichiometric coefficients, c_i, to the reactants and products: c_1 Cl_2 + c_2 C_6H_6 ⟶ c_3 HCl + c_4 C_6H_5Cl Set the number of atoms in the reactants equal to the number of atoms in the products for Cl, C and H: Cl: | 2 c_1 = c_3 + c_4 C: | 6 c_2 = 6 c_4 H: | 6 c_2 = c_3 + 5 c_4 Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c_1 = 1 and solve the system of equations for the remaining coefficients: c_1 = 1 c_2 = 1 c_3 = 1 c_4 = 1 Substitute the coefficients into the chemical reaction to obtain the balanced equation: Answer: | | Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl

+ ⟶ +

chlorine + benzene ⟶ hydrogen chloride + chlorobenzene

Construct the equilibrium constant, K, expression for: Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the activity expression for each chemical species. • Use the activity expressions to build the equilibrium constant expression. Write the balanced chemical equation: Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i Cl_2 | 1 | -1 C_6H_6 | 1 | -1 HCl | 1 | 1 C_6H_5Cl | 1 | 1 Assemble the activity expressions accounting for the state of matter and ν_i: chemical species | c_i | ν_i | activity expression Cl_2 | 1 | -1 | ([Cl2])^(-1) C_6H_6 | 1 | -1 | ([C6H6])^(-1) HCl | 1 | 1 | [HCl] C_6H_5Cl | 1 | 1 | [C6H5Cl] The equilibrium constant symbol in the concentration basis is: K_c Mulitply the activity expressions to arrive at the K_c expression: Answer: | | K_c = ([Cl2])^(-1) ([C6H6])^(-1) [HCl] [C6H5Cl] = ([HCl] [C6H5Cl])/([Cl2] [C6H6])

Construct the rate of reaction expression for: Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl Plan: • Balance the chemical equation. • Determine the stoichiometric numbers. • Assemble the rate term for each chemical species. • Write the rate of reaction expression. Write the balanced chemical equation: Cl_2 + C_6H_6 ⟶ HCl + C_6H_5Cl Assign stoichiometric numbers, ν_i, using the stoichiometric coefficients, c_i, from the balanced chemical equation in the following manner: ν_i = -c_i for reactants and ν_i = c_i for products: chemical species | c_i | ν_i Cl_2 | 1 | -1 C_6H_6 | 1 | -1 HCl | 1 | 1 C_6H_5Cl | 1 | 1 The rate term for each chemical species, B_i, is 1/ν_i(Δ[B_i])/(Δt) where [B_i] is the amount concentration and t is time: chemical species | c_i | ν_i | rate term Cl_2 | 1 | -1 | -(Δ[Cl2])/(Δt) C_6H_6 | 1 | -1 | -(Δ[C6H6])/(Δt) HCl | 1 | 1 | (Δ[HCl])/(Δt) C_6H_5Cl | 1 | 1 | (Δ[C6H5Cl])/(Δt) (for infinitesimal rate of change, replace Δ with d) Set the rate terms equal to each other to arrive at the rate expression: Answer: | | rate = -(Δ[Cl2])/(Δt) = -(Δ[C6H6])/(Δt) = (Δ[HCl])/(Δt) = (Δ[C6H5Cl])/(Δt) (assuming constant volume and no accumulation of intermediates or side products)

| chlorine | benzene | hydrogen chloride | chlorobenzene formula | Cl_2 | C_6H_6 | HCl | C_6H_5Cl Hill formula | Cl_2 | C_6H_6 | ClH | C_6H_5Cl name | chlorine | benzene | hydrogen chloride | chlorobenzene IUPAC name | molecular chlorine | benzene | hydrogen chloride | chlorobenzene

| chlorine | benzene | hydrogen chloride | chlorobenzene molar mass | 70.9 g/mol | 78.11 g/mol | 36.46 g/mol | 112.6 g/mol phase | gas (at STP) | liquid (at STP) | gas (at STP) | liquid (at STP) melting point | -101 °C | 5.5 °C | -114.17 °C | -45 °C boiling point | -34 °C | 80 °C | -85 °C | 132 °C density | 0.003214 g/cm^3 (at 0 °C) | 0.874 g/cm^3 | 0.00149 g/cm^3 (at 25 °C) | 1.106 g/cm^3 solubility in water | | | miscible | surface tension | | 0.02822 N/m | | 0.033 N/m dynamic viscosity | | 6.04×10^-4 Pa s (at 25 °C) | | 7.53×10^-4 Pa s (at 25 °C) odor | | aromatic | |